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          Shanghai Up-Fluorochem Co., Ltd.
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          Catalog No.:UPF01015

          1,1,1,3,3,3-Hexafluoroisopropyl methacrylate

          CAS No.: 3063-94-3 Name:1,1,1,3,3,3-Hexafluoroisopropyl methacrylate Purity: 98%
          MF: C7H6F6O2 MW: 236.112
          Synonyms: HFiPMA
          Details Post Buying Request
          Packing Price(RMB) LeadTime
          Customized Inquiry/negotiation 1-4 Weeks
          Note: The above price limit in China
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          Name:1,1,1,3,3,3-Hexafluoroisopropyl methacrylate

          Synonyms:

          1,1,1,3,3,3-hexafluoro-2-propanyl methacrylate

          1,1,1,3,3,3-hexafluoro-2-propyl methacrylate

          CAS No:3063-94-3

          MF:C7H6F6O2

          MW:236.112

          PSA:26.3

          LOGP:2.5989

          Appearance and shape: transparent colorless liquid

          Density: 1.302 g/mL at 25 °C (lit.)

          Boiling point: 99 oC

          Refractive index: n20/D 1.331 (lit.)

          Flash point: 58 oF

          Storage conditions: flammable area


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          Contact: Mr. Zou

          Email: info@upfluorochem.com

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          SAFETY DATA SHEETS

          According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

          Version: 1.0

          Creation Date: Aug 11, 2017

          Revision Date: Aug 11, 2017

          1.Identification

          1.1 GHS Product identifier

          Product name 1,1,1,3,3,3-hexafluoropropan-2-yl 2-methylprop-2-enoate

          1.2 Other means of identification

          Product number -
          Other names FMQPBWHSNCRVQJ-UHFFFAOYSA

          1.3 Recommended use of the chemical and restrictions on use

          Identified uses For industry use only.
          Uses advised against no data available

          1.4 Supplier's details

          Company Shanghai Up-Fluorochem Co., Ltd.
          Address T2-1623, Zhonggeng Global Creative Center, Lane 166, Minhong Road, Minhang District, Shanghai, China, 202155
          Xuhui District, Shanghai, China
          Telephone +86-18721967067
          Fax -

          1.5 Emergency phone number

          Emergency phone number Local Fire/Emergency Telephone Number

          2.Hazard identification

          2.1 Classification of the substance or mixture

          Flammable liquids, Category 2

          Acute toxicity - Oral, Category 4

          Acute toxicity - Dermal, Category 4

          Skin irritation, Category 2

          Eye irritation, Category 2

          Acute toxicity - Inhalation, Category 4

          Specific target organ toxicity – single exposure, Category 3

          2.2 GHS label elements, including precautionary statements

          Pictogram(s)
          Signal word

          Danger

          Hazard statement(s)

          H225 Highly flammable liquid and vapour

          H302 Harmful if swallowed

          H312 Harmful in contact with skin

          H315 Causes skin irritation

          H319 Causes serious eye irritation

          H332 Harmful if inhaled

          H335 May cause respiratory irritation

          Precautionary statement(s)
          Prevention

          P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

          P233 Keep container tightly closed.

          P240 Ground and bond container and receiving equipment.

          P241 Use explosion-proof [electrical/ventilating/lighting/...] equipment.

          P242 Use non-sparking tools.

          P243 Take action to prevent static discharges.

          P280 Wear protective gloves/protective clothing/eye protection/face protection.

          P264 Wash ... thoroughly after handling.

          P270 Do not eat, drink or smoke when using this product.

          P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

          P271 Use only outdoors or in a well-ventilated area.

          Response

          P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

          P370+P378 In case of fire: Use ... to extinguish.

          P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/…if you feel unwell.

          P330 Rinse mouth.

          P302+P352 IF ON SKIN: Wash with plenty of water/...

          P312 Call a POISON CENTER/doctor/…if you feel unwell.

          P321 Specific treatment (see ... on this label).

          P362+P364 Take off contaminated clothing and wash it before reuse.

          P332+P313 If skin irritation occurs: Get medical advice/attention.

          P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

          P337+P313 If eye irritation persists: Get medical advice/attention.

          P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

          Storage

          P403+P235 Store in a well-ventilated place. Keep cool.

          P403+P233 Store in a well-ventilated place. Keep container tightly closed.

          P405 Store locked up.

          Disposal

          P501 Dispose of contents/container to ...

          2.3 Other hazards which do not result in classification

          none

          3.Composition/information on ingredients

          3.1 Substances

          Chemical name Common names and synonyms CAS number EC number Concentration
          1,1,1,3,3,3-hexafluoropropan-2-yl 2-methylprop-2-enoate 1,1,1,3,3,3-hexafluoropropan-2-yl 2-methylprop-2-enoate 3063-94-3 none 100%

          4.First-aid measures

          4.1 Description of necessary first-aid measures

          General advice

          Consult a physician. Show this safety data sheet to the doctor in attendance.

          If inhaled

          If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

          In case of skin contact

          Wash off with soap and plenty of water. Consult a physician.

          In case of eye contact

          Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

          If swallowed

          Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

          4.2 Most important symptoms/effects, acute and delayed

          no data available

          4.3 Indication of immediate medical attention and special treatment needed, if necessary

          no data available

          5.Fire-fighting measures

          5.1 Extinguishing media

          Suitable extinguishing media

          Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

          5.2 Specific hazards arising from the chemical

          no data available

          5.3 Special protective actions for fire-fighters

          Wear self-contained breathing apparatus for firefighting if necessary.

          6.Accidental release measures

          6.1 Personal precautions, protective equipment and emergency procedures

          Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

          6.2 Environmental precautions

          Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

          6.3 Methods and materials for containment and cleaning up

          Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

          7.Handling and storage

          7.1 Precautions for safe handling

          Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

          7.2 Conditions for safe storage, including any incompatibilities

          Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

          8.Exposure controls/personal protection

          8.1 Control parameters

          Occupational Exposure limit values

          no data available

          Biological limit values

          no data available

          8.2 Appropriate engineering controls

          Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

          8.3 Individual protection measures, such as personal protective equipment (PPE)

          Eye/face protection

          Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

          Skin protection

          Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

          Respiratory protection

          Wear dust mask when handling large quantities.

          Thermal hazards

          no data available

          9.Physical and chemical properties

          Physical state Clear colorless liquid
          Colour no data available
          Odour no data available
          Melting point/ freezing point -20°C(lit.)
          Boiling point or initial boiling point and boiling range 120°C
          Flammability no data available
          Lower and upper explosion limit / flammability limit no data available
          Flash point 16°C(lit.)
          Auto-ignition temperature no data available
          Decomposition temperature no data available
          pH no data available
          Kinematic viscosity no data available
          Solubility no data available
          Partition coefficient n-octanol/water (log value) no data available
          Vapour pressure no data available
          Density and/or relative density 1.302 g/mL at 25oC(lit.)
          Relative vapour density no data available
          Particle characteristics no data available

          10.Stability and reactivity

          10.1 Reactivity

          no data available

          10.2 Chemical stability

          Stable under recommended storage conditions.

          10.3 Possibility of hazardous reactions

          no data available

          10.4 Conditions to avoid

          no data available

          10.5 Incompatible materials

          no data available

          10.6 Hazardous decomposition products

          no data available

          11.Toxicological information

          Acute toxicity

          • Oral: no data available
          • Inhalation: no data available
          • Dermal: no data available

          Skin corrosion/irritation

          no data available

          Serious eye damage/irritation

          no data available

          Respiratory or skin sensitization

          no data available

          Germ cell mutagenicity

          no data available

          Carcinogenicity

          no data available

          Reproductive toxicity

          no data available

          STOT-single exposure

          no data available

          STOT-repeated exposure

          no data available

          Aspiration hazard

          no data available

          12.Ecological information

          12.1 Toxicity

          • Toxicity to fish: no data available
          • Toxicity to daphnia and other aquatic invertebrates: no data available
          • Toxicity to algae: no data available
          • Toxicity to microorganisms: no data available

          12.2 Persistence and degradability

          no data available

          12.3 Bioaccumulative potential

          no data available

          12.4 Mobility in soil

          no data available

          12.5 Other adverse effects

          no data available

          13.Disposal considerations

          13.1 Disposal methods

          Product

          The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

          Contaminated packaging

          Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

          14.Transport information

          14.1 UN Number

          ADR/RID: UN3272 IMDG: UN3272 IATA: UN3272

          14.2 UN Proper Shipping Name

          ADR/RID: ESTERS, N.O.S.
          IMDG: ESTERS, N.O.S.
          IATA: ESTERS, N.O.S.

          14.3 Transport hazard class(es)

          ADR/RID: 3 IMDG: 3 IATA: 3

          14.4 Packing group, if applicable

          ADR/RID: II IMDG: II IATA: II

          14.5 Environmental hazards

          ADR/RID: no IMDG: no IATA: no

          14.6 Special precautions for user

          no data available

          14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

          no data available

          15.Regulatory information

          15.1 Safety, health and environmental regulations specific for the product in question

          Chemical name Common names and synonyms CAS number EC number
          1,1,1,3,3,3-hexafluoropropan-2-yl 2-methylprop-2-enoate 1,1,1,3,3,3-hexafluoropropan-2-yl 2-methylprop-2-enoate 3063-94-3 none
          European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.
          EC Inventory Listed.
          United States Toxic Substances Control Act (TSCA) Inventory Listed.
          China Catalog of Hazardous chemicals 2015 Not Listed.
          New Zealand Inventory of Chemicals (NZIoC) Not Listed.
          Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.
          Vietnam National Chemical Inventory Not Listed.
          Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Not Listed.

          16.Other information

          Information on revision

          Creation Date Aug 11, 2017
          Revision Date Aug 11, 2017

          Abbreviations and acronyms

          • CAS: Chemical Abstracts Service
          • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
          • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
          • IMDG: International Maritime Dangerous Goods
          • IATA: International Air Transportation Association
          • TWA: Time Weighted Average
          • STEL: Short term exposure limit
          • LC50: Lethal Concentration 50%
          • LD50: Lethal Dose 50%
          • EC50: Effective Concentration 50%

          References

          • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
          • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
          • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
          • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
          • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
          • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
          • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
          • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
          • ECHA - European Chemicals Agency, website: https://echa.europa.eu/

          Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.

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